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    14760-26-0

    Catalog No. EBD3041589

    CAS 14760-26-0

    Name 1,1,1,3,3,3-HEXAMETHYLDISILAZANE, ZINC SALT

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    Basic Information

    Synonyms: ZINCBIS(TRIMETHYLSILYL)AMIDE ZINCBIS(HEXAMETHYLDISILAZIDE) ZINCBIS[BIS(TRIMETHYLSILYL)AMIDE] 1,1,1,3,3,3-HEXAMETHYLDISILAZANE,ZINCSALT ZINCBIS[BIS(TRIMETHYLSILYL)AMIDE],1,1,1,3,3,3-HEXAMETHYLDISILAZANEZINCSALT Zincbisbistrimethylsilylamide zincbis(1,1,1,3,3,3-hexamethyldisilazan-2-ide) bis(bis(trimethylsilyl)amino)zinc

    Molecular Formula: C12H36N2Si4Zn

    Molecular Weight: 386.15

    Categories: Synthetic Chemistry > Organometallic Reagents > Organozinc Reagents Synthetic Chemistry > Catalysts and Ligands > Metal Catalysts

    Product Description:
    Zinc bis[bis(trimethylsilyl)amide], with CAS number 14760-26-0, is an organozinc compound. It is commonly represented by the formula Zn[N(SiMe₃)₂]₂. This compound is a colorless to pale yellow solid, typically handled under inert atmosphere conditions (e.g., nitrogen or argon) due to its sensitivity to air and moisture. Its primary application is as a versatile reagent in synthetic chemistry. It serves as a powerful base and a source of the bis(trimethylsilyl)amide anion. It is frequently used for the deprotonation of acidic C-H bonds, particularly in the preparation of other organometallic complexes and as a precursor in materials science, such as the synthesis of zinc oxide nanoparticles via chemical vapor deposition (CVD) or atomic layer deposition (ALD) processes. It also acts as a catalyst or catalyst precursor in various organic transformations, including hydroamination and ring-opening polymerization reactions. This reagent is valued for its steric bulk, provided by the trimethylsilyl groups, which enhances its solubility in organic solvents and modifies its reactivity. Standard safety protocols for pyrophoric and moisture-sensitive materials must be strictly followed during its handling and storage.
    Physical Properties

    Melting Point: 12-13℃

    mg g kg ml l t