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    14875-91-3

    Catalog No. EBD89645

    CAS 14875-91-3

    Name copper(II), 2,9-dimethyl-1,10-phenanthroline complex

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    Basic Information

    Synonyms: copper(II),2,9-dimethyl-1,10-phenanthrolinecomplex copper-neocuproinecomplex (NC)2Cu(I) (NC)2Cu(II) Bis(2,9-dimethyl-1,10-phenanthroline-N(1),N(10))copper(2+) Copper(2+),bis(2,9-dimethyl-1,10-phenanthroline-N1,N10)- 1,10-phenanthroline,2,9-dimethyl-,copper(2+)salt(2:1)

    Molecular Formula: C28H24CuN4

    Molecular Weight: 480.07

    Categories: Materials Chemistry > Optoelectronic and Organic Semiconductor Materials > Optoelectronic Functional Compounds Synthetic Chemistry > Catalysts and Ligands > Metal-Ligand Complexes

    Product Description:
    Copper(II) bis(2,9-dimethyl-1,10-phenanthroline) is a coordination complex where a central copper(II) ion is chelated by two molecules of 2,9-dimethyl-1,10-phenanthroline (dmp). The methyl groups at the 2 and 9 positions of the phenanthroline ligand provide steric hindrance, which significantly influences the complex's geometry, electronic properties, and stability compared to the unsubstituted 1,10-phenanthroline analog. This complex is primarily utilized in materials science and photophysics. It serves as a key component in the fabrication of organic light-emitting diodes (OLEDs), functioning as an efficient phosphorescent emitter material. The sterically hindered ligand environment helps to suppress non-radiative decay pathways and enhance photoluminescence quantum yield. Furthermore, it acts as a catalyst or catalyst precursor in various organic transformations, including oxidation reactions and C-H functionalization, leveraging the redox-active nature of the copper center. The compound is also of significant interest in fundamental research for studying electron transfer processes, supramolecular chemistry, and as a model system for understanding the photophysical behavior of transition metal complexes. It is typically handled as a solid and requires storage under inert conditions to maintain stability.
    Physical Properties

    Boiling Point: 367.4°Cat760mmHg

    Flash Point: 159.7°C

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