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    32876-92-9

    Catalog No. EBD2093423

    CAS 32876-92-9

    Name Bis(tert-butyl-cyclopentadienyl)-zirconium(iv) dichloride; Dichlorobis[(1,2,3,4,5-H)-1-(tert-butyl)-2,4-cyclopentadien-1-yl]-zirconium

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    Basic Information

    Synonyms: Bis(tert-butyl-cyclopentadienyl)-zirconium(iv) dichloride Dichlorobis[(1,2,3,4,5-H)-1-(tert-butyl)-2,4-cyclopentadien-1-yl]-zirconium Bis(t-butylcyclopentadienyl)zirconiumdichloride Bis(tert-butylcyclopentadienyl)zirconiumdichloride Bistbutylcyclopentadienylzirconiumdichloridemin Bis(tert-butyl-cyclopentadienyl)-zirconium(iv)dichloride Dichlorobis[(1,2,3,4,5-H)-1-(tert-butyl)-2,4-cyclopentadien-1-yl]-zirconium

    Molecular Weight: 333.62

    Categories: Materials Chemistry > Polymers and Macromolecular Materials > Other Polymers and Macromolecular Materials Synthetic Chemistry > Catalysts and Ligands > Metal Catalysts

    Product Description:
    Bis(tert-butylcyclopentadienyl)zirconium(IV) dichloride is a metallocene complex of zirconium. It features two tert-butyl-substituted cyclopentadienyl (Cp) ligands and two chloride ligands, forming a bent metallocene structure. This compound is a solid and is sensitive to air and moisture, requiring handling under inert atmospheres. This zirconocene dichloride derivative is primarily used as a catalyst precursor in the field of polymer chemistry. When activated with co-catalysts such as methylaluminoxane (MAO), it forms highly active catalytic systems for the polymerization of olefins, particularly ethylene and propylene. Its sterically demanding tert-butyl substituents on the Cp rings influence the catalyst's activity, stereoselectivity, and the properties of the resulting polyolefins. It serves as a key component in the development of single-site catalysts for producing polymers with controlled molecular weight and microstructure. Beyond its primary role in polyolefin catalysis, this compound is also a valuable organometallic reagent in synthetic chemistry. It is used in stoichiometric organic transformations and as a precursor for synthesizing other zirconium complexes with tailored catalytic properties for various organic reactions.
    Physical Properties

    Melting Point: 192-194 °C

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