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    376367-93-0

    Catalog No. EBD48924

    CAS 376367-93-0

    Name Firpic

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    Basic Information

    Synonyms: Bis(4,6-difluorophenylpyridine)(picolinate)iridium(III) FirPic Bis(4,6-difluorophenyl-pyridine)(picolinate)iridium(III) Bis(4,6-difluorophenyl-pyridine)?(picolinate)iridium(III) LT-E607 Bis(3,5-difluoro-2-(2-pyridyl)phenyl-(2-carboxypyridyl)iridium(III) Bis(4,6-difluorophenylpyridinato-N,C2)picolinatoiridium Bis[3,5-difluoro-2-(2-pyridinyl-kN)phenyl-kC](2-pyridinecarboxylato-kN1,kO2)-Iridium

    Molecular Formula: C28H16F4IrN3O2

    Molecular Weight: 694.67

    Categories: Materials Chemistry > Optoelectronic and Organic Semiconductor Materials > OLED and Organic Optoelectronic Precursors Materials Chemistry > Optoelectronic and Organic Semiconductor Materials > Optoelectronic Functional Compounds

    Product Description:
    FIrpic, with the chemical name bis(4,6-difluorophenylpyridinato-N,C2')iridium(III) picolinate, is a highly efficient greenish-blue phosphorescent organometallic complex. It features an octahedral coordination geometry around the central iridium(III) ion, coordinated by two cyclometalated 4,6-difluorophenylpyridine ligands and one picolinate ancillary ligand. This specific ligand design is crucial for tuning its photophysical properties. Its primary and most significant application is as a dopant emitter in the emissive layer of Organic Light-Emitting Diodes (OLEDs). FIrpic exhibits strong phosphorescence from a triplet excited state, enabling theoretically 100% internal quantum efficiency in OLED devices. It is one of the benchmark materials for achieving blue and greenish-blue emission in both academic research and commercial display/lighting technologies. The fluorine substitution on the phenylpyridine ligands helps to raise the triplet energy level and improve color purity. The compound is typically supplied as a yellow crystalline powder and requires handling under inert atmosphere (e.g., nitrogen or argon glovebox) due to its sensitivity to moisture and oxygen, which can lead to decomposition and quenching of its luminescent properties. Its synthesis and purification are critical steps to ensure high performance in final OLED devices.
    Physical Properties

    Melting Point: 330-335 °C

    mg g kg ml l t