dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct, CAS No. 95464-05-4

Welcome to iChemical.com!

In the below part, please select the country you want us to ship to: Please note that once you've selected a shipping country, all pricing information on our website will be automatically updated to include door-to-door shipping to the country you specified.

North America

South America

Africa

Europe

Asia

Oceania

95464-05-4

Catalog No. EBD10945

CAS 95464-05-4

Name dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct

Get Quote

Basic Information

Synonyms: PdCl{2}(dppf)^.CH{2}Cl{2} dichloro[1,1'-bis(diphenylphosphino)ferrocene]-palladiumdichloromethaneadduct dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(ii)dichloromethaneadduct dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(ii)dichloromethanecomplex 1,1'-bis(diphenylphosphino)ferrocenepalladium(ii)dichloride,dichloromethane 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloridedichloromethanecomplex [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(ii),complexwithdichloromethane(1:1) [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(ii),dcmadduct [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(ii),dichloromethaneadduct Pd(dppf)2Cl2 [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II)chloride,complexwithdichloromethane [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II)chloride,complex

Molecular Formula: C35H30Cl4FeP2Pd

Molecular Weight: 816.64

MDL Number: MFCD00792899

Categories: Synthetic Chemistry > Catalysts and Ligands > Metal-Ligand Complexes

Product Description:

Dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct, commonly known as Pd(dppf)ClВ╖CHВClВ, is a palladium(II) complex coordinated with the bidentate phosphine ligand 1,1'-bis(diphenylphosphino)ferrocene (dppf). It is a dark red to brown crystalline solid, often supplied as a dichloromethane adduct for enhanced stability and solubility. This compound is a highly versatile and widely used catalyst in cross-coupling reactions, including Suzuki-Miyaura, Stille, Negishi, and Buchwald-Hartwig amination reactions. The dppf ligand provides strong electron-donating properties and a large bite angle, which facilitates oxidative addition and reductive elimination steps, making it particularly effective for challenging couplings involving sterically hindered or electron-rich substrates. Pd(dppf)ClВ╖CHВClВ is air-stable and easy to handle, making it a preferred choice in both academic research and industrial-scale pharmaceutical synthesis. It is also employed in carbonylation reactions and C-H activation processes. Due to its high catalytic activity and broad substrate scope, it is a staple in organanometallic chemistry and fine chemical manufacturing.

Physical Properties

Melting Point: 275-280 °C(lit.)

Density: 1 g/cm3